Subtle Chemistry Matters in Linking Partners in Compounds When it Comes to a New Type of Superconductors, According to CSUN Prof
A subtle chemical interaction between metal and anion sublattices, not between atoms, in compounds matters when it comes to superhydrides — a new type of high-pressure compound with exceedingly high hydrogen composition and the ability to conduct electricity without energy loss when cooled below a critical temperature.
In particular, metal superhydrides could help provide the answers scientists have been looking for in their efforts to find ways to allow superconductivity without having to reduce the temperature to extremely low levels, according to California State University, Northridge chemistry professor Maosheng Miao, who is among the eight recipients of the prestigious 2022 Henry-Dreyfus Teacher-Scholar award.
“The holy grail for a lot of materials scientists is room-temperature superconductivity,” said Miao, who teaches in CSUN’s College of Science and Mathematics. “The technology created by superconductivity is vital to so many parts of our lives. For instance, the MRI (magnetic resonance imaging) scans that are so important in the medical world are done by huge devices. Much of that machinery is used to keep temperatures cool to allow superconductivity to take place to create a strong magnetic field. Now, imagine if you could take those scans with machines that don’t need to be kept at a certain temperature? That could revolutionize medicine, and a whole lot of other industries that rely on superconductivity, as well.”
Miao said a new hope for that revolution might lie in metal superhydrides, chemical compounds that contain an abnormally large amount of hydrogen.
“Since superconductivity was first discovered in 1911, people have been trying to find a way to make it happen at room temperature,” Miao said. “The recent discovery of superhydrides a few years ago brought us very close to room-temperature superconductivity that could potentially transform energy transportation and many other technologies. But efforts to improve superconductivity by raising the temperature and lowering the pressure on superhydrides are set back by the complexity of the structures and not knowing the chemical force that drives the formation of these compounds.”
Determined to find the answers, Miao — a computational chemist who studies atoms and bonds and how they change under high pressure — proposed that metal lattice in superhydrides form templates that assist the formation of hydrogen covalent networks and applied computer simulations based on quantum mechanics to demonstrate and quantize this subtle chemistry.
His findings, “Chemical templates that assembly metal superhydrides,” was recently published in the journal Chem . The co-author of this two-author paper is Yuanhui Sun, a research scholar in CSUN’s Department of Chemistry.
“If you want to understand superhydrides,” he said, “you have to change your view. It is not the chemistry between the individual atoms, but the chemistry between metal sublattice and hydrogen sublattice that matters. We first remove all the hydrogens from superhydrides and see the behavior of electrons in what is left.”
Miao and Sun showed that the electrons in the metal sublattice (“what is left”) occupy the quantum orbitals located in the major voids between metal atoms. Since these local orbitals behave the same way as atomic orbitals, they call these voids “quasi-atoms”. While they overlay the hydrogen lattice on top of the electron state of the metal lattice, a harmonic relation emerges – they match perfectly, as if the electrons in the metal lattice form a template that awaits and assists the assembly of the hydrogen network.
One key point was that the template effect is not found in all metals, Miao said.
“This template, this driving force, explains beautifully why some metals can form superhydrides and other metals, like aluminum, cannot,” he said, adding that the theory goes beyond superhydrides.
“It’s a general chemical bond theory,” Miao said. “This template effect exists in many composites, including table salt. And because it’s so subtle, that may be one of the reasons people haven’t look at it for the role it plays in superhydrides before now.”
Miao said he hopes his findings will move the conversation forward as scientists continue their search for room-temperature superconductivity.
“The theory significantly improves the efficiency of searching for new complex superhydrides by screening the metal templates,” he said. “Our work goes beyond superhydrides and transforms the empirical anion-in-metal approach into a true bond theory that can greatly enhance the efficiency of searching for new compounds and can resolve many puzzles in solid-state chemistry.”